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Z. Naturforsch. 2013,
68b, 357 – 361
doi:10.5560/ZNB.2013-3013
Mixed Linker Strategy for the Construction of a Fluorescent 2D Network Based on [Ag2(COO)2] as Secondary Building Unit
School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100, P. R. China
Reprint requests to Dr. Di Sun. Fax: +86-531-88364218. E-mail:
dsun@sdu.edu.cn
Received January 16, 2013 / published online April 19, 2013
The ultrasound-assisted reaction of AgNO3, 2-amino-4,6-dimethylpyrimidine (dmapym) and 2,6-naphthalenedicarboxylic acid (H2npd) gave rise to a new 2D network of the formula [Ag2(dmapym)2(npd)]n (1). The atoms Ag1 and Ag2 in the complex show seesaw and distorted tetrahedral coordination geometries, respectively. The dmapym ligand acts as a bidentate bridge to bind paired Ag(I) ions into a chain. The chains are further connected by npd linkers to form the resultant 2D network reinforced by N–H···O hydrogen bonds between dmapym and npd. Weak C–H···π interactions are also found in the crystal structure. Complex 1 exhibits photoluminescence in the solid state at room temperature with an emission maximum at 418 nm upon excitation at 330 nm.
Key words: Silver(I), 2-Amino-4,6-dimethylpyrimidine, 2,6-Naphthalenedicarboxylic Acid, Photoluminescence
Supporting Material: