Graphical Abstracts Vol. 68b (2013)
N u m b e r  5 / 6
Cover Page
To Professor Heinrich Nöth on the Occasion of his 85th Birthday
Hubert Schmidbaur, Rainer Pöttgen, Gerhard Maas, Thomas Lindel, Annette Schier, Gerhard Müller, and Tamina Greifeld
409 Open Access


Regioselective Functionalization of Pyridines using a Directed Metalation or a Halogen/Metal Exchange
Sophia M. Manolikakes, Nadja M. Barl, Christoph Sämann, and Paul Knochel
411  Full Text

Fluorescence Microscopy Studies of Porous Silica Materials
Bastian Rühle, Melari Davies, Thomas Bein, and Christoph Bräuchle
423  Full Text

Original Communications

Coordination of N-Heterocyclic Carbene to H2SiX2 (X = Cl, OTf) and H3SiOTf (OTf = OSO2CF3): Synthesis of Donor-stabilized Parent Silylium Salts with Four- and Five-coordinate Silicon Atoms
Yun Xiong, Shenglai Yao and Matthias Driess
445  Full Text

N-Heterocyclic Carbene-facilated Condensation of 3-Methylphenylboronic Acid to the Boroxine
Dongxiang Zhang, Jie Li, Xiao Dong, Xing Zhou, Zhi Yang, and Herbert W. Roesky
453  Full Text

Nickel(II) and Iron(II) Complexes with Tetradentate NHC/Amide Hybrid Ligands
Iris Klawitter, Steffen Meyer, Serhiy Demeshko, and Franc Meyer
458  Full Text

Ligand Exchange at a Gold(I) Carbene Complex
Mareike C. Jahnke, Tania Pape and F. Ekkehardt Hahn
467  Full Text

Amine Complexes of Gold, Part 7: Pseudosymmetry in Amine Complexes of Gold(I) Cyanide (In German)
Cindy Döring and Peter G. Jones
474  Full Text

Cyclic Alkyl(aryl)boranes for 1,1-Carboboration of Monoalkynyltin Compounds
Bernd Wrackmeyer, Peter Thoma and Wolfgang Milius
493  Full Text

Hydroalumination versus Deprotonation of Alkynes with Sterically Demanding Substituents
Werner Uhl, Marcus Layh, Ines Rhotert, Agnes Wollschläger, and Alexander Hepp
503  Full Text

Synthesis and Characterization of Strontium Bis(N-isopropylanilide) and Comparison with the Lighter Magnesium and Calcium Congeners
Claas Loh, Carsten Glock, Steffen Ziemann, Helmar Görls, Sven Krieck, and Matthias Westerhausen
518  Full Text

Preparation of CaCO3 and CaO Replicas Retaining the Hierarchical Structure of Spruce Wood
Somruedee Klaithong, Daniel Van Opdenbosch, Cordt Zollfrank, and Johann Plank
533  Full Text

The 1:1 Adduct of 1,3-Diisopropyl-4,5-dimethyl-2,3-dihydroimidazol-2-ylidene and Nitrous Oxide
M. Göhner, P. Haiss, N. Kuhn, M. Ströbele, and K.-P. Zeller
539  Full Text

Coordination Chemistry of Polynitriles, I. Syntheses and Crystal Structures of [Ag(PCC)(DMF)], [Ni(DMF)6](PCC)2 and [Co(DMF)6](PCC)2 (PCC = [C5(CN)5], DMF = N,N-Dimethylformamide)
Karlheinz Sünkel and Dietmar Reimann
546  Full Text

Synthesis and Coordination Chemistry of a Tris(benzene-o-dithiolato)-functionalized Ligand as a Siderophore Analog
Susanne Ruppel, Christian Schulte to Brinke and F. Ekkehardt Hahn
551  Full Text

A Dinuclear Palladium(II) Complex of the {N(SPPh2)2} Ligand – Synthesis and Structure
Sebastian Marks and Peter W. Roesky
557  Full Text

Heterometallic Complexes with Rhenium- and Iron-Bismuth Bonds
Rafael Schiwon, Ramona Metzinger, Christina Pfirrmann, and Christian Limberg
561  Full Text

Isolation, Optical Properties and Core Structure of a Water-soluble, Phosphine-stabilized [Au9]3+ Cluster
Benjamin S. Gutrath, Carina Merkens, Frank Schiefer, Ulli Englert, Günter Schmid, and Ulrich Simon
569  Full Text

[Cu40Se16(S-C6H4-CN)8(dppm)8]: A Disc-like Copper Cluster with a Nitrile-functionalized Ligand Shell
Robert Langer, Dieter Fenske and Olaf Fuhr
575  Full Text

Ferromagnetism and the Formation of Interlayer As2 Dimers in Ca(Fe1−xNix)2As2
Roman Pobel, Rainer Frankovsky and Dirk Johrendt
581  Full Text

Oxidation Reactions Catalyzed by Polyoxomolybdate Salts
Bo Zhang, Su Li, Alexander Pöthig, Mirza Cokoja, Shu-Liang Zang, Wolfgang A. Herrmann, and Fritz E. Kühn
587  Full Text

Synthesis and Characterization of Imidazolium Perrhenate Ionic Liquids
Shuang Yue, Da-Wei Fang, Jun Li, Shu-Liang Zang, Ming-Dong Zhou, Bo Zhang, Iulius I. E. Markovits, Mirza Cokoja, and Fritz E. Kühn
598  Full Text

Infinite Anionic Chains Formed by Alternating Bidentately Acting [SbS4]3− Anions and [Mn(dien)]2+ Complexes in the Compound [Mn(dien)2][Mn(dien)SbS4]2
Nicola Herzberg, Christian Näther and Wolfgang Bensch
605  Full Text

Novel Polyanionic Topologies in Ag2VAsO6 and Ag6V2As2O13
Jürgen Nuss, Jan Curda and Martin Jansen
611  Full Text

Syntheses and Crystal Structures of the Bromide-derivatized Lanthanoid(III) Ortho-Oxomolybdates(VI) LnBr[MoO4] (Ln = Pr, Nd, Sm, Gd–Lu)
Tanja Schustereit, Harald Henning, Thomas Schleid, and Ingo Hartenbach
616  Full Text

Single-crystal Data of Ternary Germanides RE2Nb3Ge4 (RE = Sc, Y, Gd–Er, Lu) and Sc2Ta3Ge4 with Ordered Sm5Ge4-type Structure
Bastian Reker, Samir F. Matar, Ute Ch. Rodewald, Rolf-Dieter Hoffmann, and Rainer Pöttgen
625  Full Text

RE4B4O11F2 (RE = Pr, Nd): Two New Rare-earth Fluoride Borates Isotypic to Gd4B4O11F2
Matthias Glätzle and Hubert Huppertz
635 Open Access

Synthesis, Crystal Structures and Polymorphism of New Cadmium and Zinc Thio- and Selenocyanato Coordination Compounds with 4-Acetylpyridine as N-Donor Ligand
Julia Werner, Inke Jess and Christian Näther
643  Full Text

Novel Tin(IV) Complexes with the Hybrid Guanidine Ligand DMEGqu
Anton Jesser, Ines dos Santos Vieira and Sonja Herres-Pawlis
653  Full Text

Facile 1,1-Carboboration Reaction of a Diarylphosphino-substituted Conjugated Diyne with Tris(pentafluorophenyl)borane
Philipp Feldhaus, Gerald Kehr, Roland Fröhlich, Constantin G. Daniliuc, and Gerhard Erker
666  Full Text

New Pulvinic Acid and Phenylalaninol Derivatives from the Mushrooms Retiboletus griseus and R. nigerrimus
Gertraud Gruber, Lydia Kerschensteiner, Ryuji Marumoto, and Wolfgang Steglich
675  Full Text

NIR Absorption of Perylene Dyes and Fluorescence with Large Stokes' Shift by Simple Deprotonation
Heinz Langhals and Maximilian Rauscher
683  Full Text

Molecular and Crystal Structure of Chlorido[2-(N,N,N′,N′-tetramethylamidinio)ethynido]silver
Werner Weingärtner and Gerhard Maas
687  Full Text

Nucleophilic Reactivities of Schiff Bases
Biplab Maji and Herbert Mayr
693  Full Text

Synthesis of 6-Ethyl-1,2,9-trioxopyrrolo[3,2-f]quinoline-8-carboxylic Acid
Randa M. Al-As'ad, Mustafa M. El-abadelah, Salim S. Sabri, Jalal A. Zahra, and Wolfgang Voelter
700  Full Text

Synthesis of a 30-Membered Macrocycle Incorporating Two Ruthenium Sandwich Complexes
Alexander Schmid, Kurt Polborn and Thomas Lindel
707  Full Text

Novel Insensitive Energetic Nitrogen-rich Polymers Based on Tetrazoles
Franziska M. Betzler, Ruth Boller, Adriana Grossmann, and Thomas M. Klapötke
714  Full Text

Structures of Energetic Acetylene Derivatives HC≡CCH2ONO2, (NO2)3CCH2C≡CCH2C(NO2)3 and Trinitroethane, (NO2)3CCH3
Thomas M. Klapötke, Burkhard Krumm, Richard Moll, Alexander Penger, Stefan M. Sproll, Raphael J. F. Berger, Stuart A. Hayes, and Norbert W. Mitzel
719  Full Text


First Incorporation of the Tetrahedral [Sn4]4− Cluster into a Discrete Solvate Na4[Sn4]·(NH3)13 from Solutions of Na4Sn4 in Liquid Ammonia
Markus Waibel and Thomas F. Fässler
732  Full Text

Synthesis and Structure of 2,2,2-Nitrilotriacetyl Chloride with a Flat NC3 Pyramide
Thomas M. Klapötke, Burkhard Krumm and Richard Moll
735  Full Text

Cobalt(III)-Binding of Gluconate and 2-Amino-2-Deoxy-Gluconate
Max Pfister, Sarah Illi and Peter Klüfers
739  Full Text

Activation of C–Cl Bonds: Synthesis and Structural Characterization of [Ru2(μ-Cl)(μ-PtBu2)(μ-Ph2PN(H)PPh2)(CO)4]
Tobias Mayer and Hans-Christian Böttcher
743  Full Text

A Base-stabilized Iodoborylene Complex of Platinum(II)
Holger Braunschweig, Peter B. Brenner, Rian D. Dewhurst, and Krzysztof Radacki
747  Full Text