Z. Naturforsch. 2014, 69b, 1241 – 1247
The Synthesis and Characterization of Nitrooxy- and Nitrosooxyborazine Compounds
Thomas M. Klapötke and Magdalena Rusan
Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstr. 5–13 (D), 81377 Munich, Germany
Reprint requests to Prof. Dr. Thomas M. Klapötke. Fax: +49-89-2180-77492. E-mail: tmk@cup.uni-muenchen.de
Received May 19, 2014 / published online December 19, 2014
Dedicated to Professor Hubert Schmidbaur on the occasion of his 80th birthday
B-Nitrosooxypentamethylborazine, B-nitrooxypentamethylborazine and B-trinitrooxy-N-trimethylborazine have been synthesized and characterized by 1H, 13C, 11B, and 14N NMR spectroscopy, mass spectrometry, vibrational spectroscopy and elemental analysis. The 11B NMR shifts were calculated and compared to the experimental results. The decomposition temperatures and the impact and friction sensitivities of these compounds have been determined as well.
Key words: Nitrosooxyborazines, Nitrooxyborazines, 11B NMR Spectroscopy, Energetic Materials, Impact and Friction Sensitivities
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