Z. Naturforsch. 2013,
68b, 1333 – 1339
doi:10.5560/ZNB.2013-3185
Synthesis, Structure and Properties of a 2D Cadmium(II) Coordination Polymer Based on Fluconazole and Isophthalate Ligands
Gang-Hong
Pan,
Jing-Niu
Tang,
Xian-Hong
Yin,
Wei-Man
Tian, and
Zhong-Jing
Huang
College of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, P. R. China
Received June 17, 2013 / published online November 22, 2013
A Cd(II) complex based on fluconazole and isophthalate ligands, {[Cd(HFlu)(IPA)(H2O)]·H2O}n (1), (HFlu = fluconazole; H2IPA = isophthalic acid) has been synthesized. Single-crystal X-ray analysis reveals that complex 1 has a 2D network structure including unusual triple hydrogen bonds between hydroxyl and triazolyl groups. The complex has also been characterized by IR, UV/Vis and fluorescence spectroscopy, elemental analysis, and thermogravimetry.
Key words: Triple Hydrogen Bond, Coordination Polymer, Fluconazole, UV/Vis Spectra, Fluorescence, Thermogravimetry